Please use this identifier to cite or link to this item: http://cris.utm.md/handle/5014/434
Title: Optical properties and birefringence of ZnIn2S4 layered crystals
Authors: STAMOV, Ivan 
ZALAMAI, Victor 
SIRBU, Nicolae 
TIRON, Andrei 
Keywords: birefringence;Frenkel excitons;Interference spectra;refractive indices;Band structure
Issue Date: 2020
Source: STAMOV, Ivan; ZALAMAI, Victor; SYRBU, Nicolae; TIRON, Andrew. Optical properties and birefringence of ZnIn2 S4 layered crystals. In: Physica E: Low-Dimensional Systems and Nanostructures. 2020, nr. 115, p. 0. ISSN -.10.1016/j.jpcs.2019.05.013
Journal: Physica E: Low-Dimensional Systems and Nanostructures 
Abstract: 
Interference spectra of layered ZnIn2S4 crystals were investigated for samples of different thicknesses (7.5–900 μm). Spectral dependences of refractive indices (na and nb) for light waves with different polarizations were calculated and their intersection observed at energy E0 ∼ 2.38 eV. The refractive indices difference (Δn = na − nb) was determined at energy range 0.8–3.0 eV. Features observed in reflection and absorption spectra were attributed to the band-to-band electron transitions at k = 0. Magnitudes of valence bands (V1, V2 and V3, V4) splitting due to crystal field and spin–orbital interaction were determined. Electron transitions in energy interval 2–6 eV were identified on the basis of available theoretical band structure calculations.
URI: http://cris.utm.md/handle/5014/434
ISSN: 0022-3697
DOI: 10.1016/j.jpcs.2019.05.013
Appears in Collections:Journal Articles

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