Please use this identifier to cite or link to this item: http://cris.utm.md/handle/5014/801
Title: Up-conversion luminescence in GaSe nanocrystals
Authors: SIRBU, Nicolae 
STAMOV, Ivan 
DOROGAN, Andrei 
ZALAMAI, Victor 
Keywords: Gallium selenide;Up-conversion process;Luminescence;Excitionic states;Optical spectroscopy;Effective mass
Issue Date: 2021
Source: N.N. Syrbu, I.G. Stamov, A.V. Dorogan, V.V. Zalamai, Up-conversion luminescence in GaSe nanocrystals, Optical Materials, Volume 111, 2021, 110675, ISSN 0925-3467, https://doi.org/10.1016/j.optmat.2020.110675.
Project: 20.80009.5007.20. Nanoarhitecturi în bază de GaN şi matrici tridimensionale din materiale biologice pentru aplicaţii în microfluidică şi inginerie tisulară 
Journal: Optical Materials 
Abstract: 
Optical properties of GaSe crystals have been investigated at wide temperature range from 10 to 300 K by help of reflection, absorption, and wavelength modulated reflection, and transmission spectra. Received data were compared with measured photoluminescence spectra. Three excitonic series were found out. The parameters of excitonic serie for С1-V1 bnads were determined. The longitudinal-transversal splitting of excitonic polariton ground states were determined. The doublet character of the transversal excitonic polariton mode (ωТ) was found out. The ground (n = 1) and excited (n = 2,3 … Eg) states of two high-energy excitonic series caused by C2–V1 and С3-V1 bands had been recognized, and its parameters were determined. The up-conversion of luminescence from high-energy excitonic levels (Е > 3 eV) was studied. The electrons were excited from V1 (Г1) to C1 (Г6) and C2 (Г5) bands with further transitions to higher energy levels С3-С6. So the luminescence from the excitonic levels of C3-С6 bands towards valence bands takes place. The band model in the Brillouin zone centerwas constructed based on the obtained data.
URI: http://cris.utm.md/handle/5014/801
DOI: 10.1016/j.optmat.2020.110675
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