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Title: | Aero-TiO2 Prepared on the Basis of Networks of ZnO Tetrapods | Authors: | CIOBANU, Vladimir URSAKI, Veaceslav LEHMANN, Sebastian BRANISTE, Tudor RAEVSCHI, Simion ZALAMAI, Victor MONAICO, Eduard V. COLPO, Pascal NIELSCH, Kornelius TIGINYANU, Ion |
Keywords: | aero-TiO2;atomic layer deposition;titania;anatase;rutile;spinel;zinc titanate;sacrificial template;annealing;luminescence | Issue Date: | 2022 | Publisher: | MDPI | Source: | Ciobanu, V.; Ursaki, V.V.; Lehmann, S.; Braniste, T.; Raevschi, S.; Zalamai, V.V.; Monaico, E.V.; Colpo, P.; Nielsch, K.; Tiginyanu, I.M. Aero-TiO2 Prepared on the Basis of Networks of ZnO Tetrapods. Crystals 2022, 12, 1753. https://doi.org/10.3390/cryst12121753 | Project: | 20.80009.5007.20. Nanoarhitecturi în bază de GaN şi matrici tridimensionale din materiale biologice pentru aplicaţii în microfluidică şi inginerie tisulară NanoMedTwin - Promoting smart specialization at the Technical University of Moldova by developing the field of Novel Nanomaterials for BioMedical Applications through excellence in research and twinning (#810652) |
Journal: | Crystals | Abstract: | : In this paper, new aeromaterials are proposed on the basis of titania thin films deposited using atomic layer deposition (ALD) on a sacrificial network of ZnO microtetrapods. The technology consists of two technological steps applied after ALD, namely, thermal treatment at different temperatures and etching of the sacrificial template. Two procedures are applied for etching, one of which is wet etching in a citric acid aqua solution, while the other one is etching in a hydride vapor phase epitaxy (HVPE) system with HCl and hydrogen chemicals. The morphology, composition, and crystal structure of the produced aeromaterials are investigated depending on the temperature of annealing and the sequence of the technological steps. The performed photoluminescence analysis suggests that the developed aeromaterials are potential candidates for photocatalytic applications. |
Description: | Issue 12, 1753 |
URI: | http://cris.utm.md/handle/5014/1537 | DOI: | 10.3390/cryst12121753 |
Appears in Collections: | Journal Articles |
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Ciobanu crystals-12-01753.pdf | 2.72 MB | Adobe PDF | View/Open |
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